Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile   总被引：1，自引：0，他引：1  

Santiago Andrade  James Moffett  Juan A. Correa   《Marine Chemistry》2006,101(3-4):203-212

The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu²⁺ concentrations in excess of 10^− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu²⁺ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.  相似文献   

Study of macroaggregate composition using FT-IR and H-NMR spectroscopy     

N. Kovac  O. Bajt  J. Faganeli  B. Sket  B. Orel 《Marine Chemistry》2002,78(4)

Mucous macroaggregates, recently observed in the northern Adriatic in summer of 1997 and late spring of 2000, are primarily the product of phytoplankton (diatom) exudates during favourable environmental conditions in late spring, and can be viewed as macrogels. The FT-IR and ¹H-NMR spectra of macroaggregate samples from the northern Adriatic, collected in different formation stages in July 1997, August 1997, September 1997 and June 2000, as well as of cultured diatom Skeletonema costatum, showed that they are similar and composed of aliphatic components and polysaccharides bonded through carboxylic and amide groups, and organosilicon compounds. The stability of macrogels of macroaggregates is, according to FT-IR and X-ray analyses, most probably enhanced by interactions with entrapped particles of calcite, quartz and clay minerals. These organic-mineral associations seem to be important for mucous phenomena. According to ¹H-NMR spectra, the temporal differences in macroaggregate composition show a relative increasing percentage of organosilicon compounds and aliphatic components bonded to carbohydrates through ester and amide groups, and an increasing ratio between aliphatic structures and carbohydrates. This indicates that aliphatic chains bonded to Si and carbohydrates may contribute to the persistence and stability of macroaggregates in the summer stratified waters in the northern Adriatic, while the temporal decrease of carbohydrate content is most probably due to microbial and photochemical degradation of algal reserve polysaccharides.  相似文献   

Identification of constitutive androstane receptor cDNA in northern fur seal (Callorhinus ursinus)     

Hiroki Sakai  Hisato Iwata  Eun-Young Kim  Shinsuke Tanabe  Norihisa Baba 《Marine environmental research》2004,58(2-5):107

  相似文献   

杰氏风暴潮预报方法在珠海及粤西海域的应用     

魏晓宇  窦金来  黄根华  周求赞  陈强  王欣睿 《台湾海峡》2007,26(2):197-203

本文通过杰氏风暴潮预报方法对历史上给珠海和粤西海域造成较大影响的台风增水事件进行后报试验,并通过统计分析方法对原有的预报公式进行订正,总结出适合珠海及粤西海域的风暴潮预报公式.利用5a的时间对珠海及粤西海域的台风增水进行试报,结果表明预报准确率分别达95.0%和87.6%,尤其对一些增水较大、影响较严重的台风增水预报相对更加准确,预报准确率均达90.0%以上.这说明订正后的公式对珠海及粤西海域的风暴潮预报能得到较好的预报效果.  相似文献   

南海北部深水盆地沉积-构造的差异性及其油气意义   总被引：5，自引：3，他引：2  

吕宝凤  袁亚娟 《大地构造与成矿学》2008,32(4)

南海北部深水区自西向东依次分布着琼东南盆地、珠江口盆地、台西南盆地等新生代被动陆缘盆地,这些盆地经历了大致相当的从裂陷到坳陷的构造演化史,但在张裂活动过程中存在着明显的沉积-构造的差异性。构造沉降特征分析显示:在同一构造带上自西向东有盆地主要构造沉降发生的时段逐步变晚的趋势;在不同构造带上自北向南有盆地主要构造沉降发生的时段逐步变晚的趋势。这种沉积-构造的差异性对烃源岩的发育类型、分布及生储盖组合等方面有明显的控制作用,表现为:裂谷期构造沉降幅度大的盆地,陆相烃源岩发育,以陆生陆储陆盖型成藏组合为主;裂后期构造沉降幅度大的盆地,海相烃源岩发育规模较大,海生海储海盖型成藏组合及混生海储海盖型生储盖组合所占分量逐渐增多。推测渐新统湖相-湖沼相及海陆过渡相源岩和中新统海相烃源岩应是南海北部深水区油气的主要来源,陆生海储海盖型、海生海储海盖型及混生海储海盖型生储盖组合应是深水区基本生储盖组合类型。  相似文献   

粤东成矿地质背景及银-铜-铅-锌成矿物质来源探讨     

郭锐  曾国光 《矿产与地质》2008,22(3):236-240

通过对粤东地区地层和岩石中成矿元素含量和区域地质背景的分析,认为粤东地区铜铅-锌-银成矿作用与燕山期的构造-岩浆作用关系密切,成矿物质中银-铜-锌以下地壳来源为主,铅则以上地壳及沉积地层来源为主。  相似文献   

广东省五华县地质灾害形成特征及防治对策   总被引：6，自引：0，他引：6  

罗迎新 《中国地质灾害与防治学报》2008,19(3):96-101

五华县主要地质灾害类型有滑坡、崩塌、地面塌陷、水土流失等。其中以滑坡、崩塌为主,多分布在东南、南部花岗岩区、北部花岗岩风化土区等广大中低山及丘陵区,具有点多面广,灾害点个体规模小,稳定性差,活动频繁,地质灾害发育呈明显的地域性与季节性分布等特点。五华县地质灾害的形成与发生是多种致灾因素相互作用的结果。地层岩性是其形成的内在要素,它在一定程度上决定着地质灾害的发育程度与类型;地形地貌与植被是地质灾害形成的外在条件,它制约着崩、滑、塌等致灾地质作用的形成;大气降雨是地质灾害形成与发生的激发因素,决定着地质灾害发生的速度和时间;人类工程活动是影响地质灾害形成与发生的最主要、最直接的因素。对地质灾害的防治应采用避让、预防、监测及治理措施,做到避让与治理结合,以群测群防为基本手段,点状灾害以工程治理与生物防治为主;面状灾害以生物防治为主;采用点、面结合综合治理的方法。  相似文献   

浙北双溪坞群的构造特征及地质意义   总被引：1，自引：0，他引：1  

竺国强  陈梓军 《高校地质学报》1996,2(1):58-64

本文在野外地质工作基础上,通过对双溪坞群的岩层对比和构造分析,认为本区的双溪坞群与上覆地层间在构造样式上的存在着较大差异。双溪坞群的章村组和北组具有相似的地质特征,为同一火山放心回的产物。神功运动使早期形成的双溪坞群褶皱造山,开怀 竖线型平臣褶皱构造,并受后期构造的叠加改造,形成轴向北东的叠加褶皱构造格局。  相似文献   

Sedimentary Features of Shallow Ancient River Channels on the Northern Shelf of the South China Sea   总被引：1，自引：0，他引：1  

Kou Yangqi  Du Deli nd Marine Geological Investigation Party  MGMR  Guangzhou  Guangdong Jiang M inxi 《《地质学报》英文版》1995,69(1)

Quaternary buried ancient river channels are widespread in the shallow-level sediments of the northern shelf of the South China Sea. The sedimentary sequence mainly of fluvial deposits comprise an important component part of the low-stand system tract and transgressive system tract in the study region. The plannar variation and spatial association of the sedimentary features such as incised valley fillings, deltaic foreset wedges and block slides of shelf-marginal fans reflect the palaeogeographic environment during the fall of the regional sea level in the northern part of the South China Sea. Based on the high-resolution seismic reflection data and gelogical data from boreholes, the present paper makes an integrated interpretation of the Quaternary ancient river channels in the shallow sediments of the study area, studies the sedimentary features of the ancient channels such as their spatial distribution, seismic facies reflection indicators, sedimentary facies and sand -body types, and discusses thei  相似文献   

基于泛珠三角的广东工业旅游探讨     

甘军丽 《云南地理环境研究》2006,18(2):100-103

基于建立泛珠三角的研究背景，通过对广州发展工业旅游的条件的分析得出结论，认为由于地缘关系和历史原因，在泛珠三角的成员中，广东最早接受香港地区的经济辐射，港澳台投资者在广东大量投资建厂，工业优势也日渐凸显，这种得天独厚的优势，为广东发展工业旅游奠定了坚实的基础。并通过对广东工业旅游示范点和其他适合发展工业旅游的企业进行调查分析和实证研究，总结了广东发展工业旅游的主要客源类型，并对广东工业旅游的发展提出了几点发展思路。工业与旅游相结合，两者完全可以达到双赢，并可以得到一定的社会效益，也是结论性认识。  相似文献